Adsorption of Azocarmine G dye on H2SO4-modified acacia sawdust

Abstract

Presence of hazardous dyes in water cause considerable risks to the human health and environment due to their potential toxicity and ecological disruptions. Therefore, in the present research, to suggest an alternative method for the retention of toxic Azocarmine G (ACG) dye from aqueous media, natural and H2SO4-modified acacia sawdust were performed for the first time as low-cost and efficient adsorbents. Based on batch experiments, it was determined that the best conditions for the developed dye retention process were an initial pH of 2.0 and an equilibrium time of 240 min. Analysis of the data using both pseudo-first order and pseudo-second order kinetic models showed that the retention of ACG onto the adsorbents predominantly occurred through chemical adsorption. Langmuir, Freundlich, and Dubinin-Radushkevich isotherm models were employed to provide insights into the interaction between the adsorbate and adsorbent and the mechanism of the adsorption process. Maximum monolayer adsorption capacities of natural and H2SO4-modified acacia sawdust were determined as 28.01 and 64.90 mg g-1, respectively by Langmuir isotherm model. Results of the study clearly indicated that the modification of acacia sawdust with H2SO4 leads to a substantial increase in the adsorption performance of anionic dyes. © 2024 Techno-Press, Ltd.