Dehydrated hazelnut husk carbon: a novel sorbent for removal of Ni(II) ions from aqueous solution

Abstract

The present study has been performed to examine the adsorption ability of novel sorbent dehydrated hazelnut husk carbon (DHHC) towards Ni(II) ions from aqueous solution using the batch adsorption technique. The effective factors such as initial pH of the aqueous solution, contact time, initial Ni(II) concentration, adsorbent dosage, and temperature were investigated. The studies were also conducted to understand the effect of some co-existing ions which may be present in aqueous solutions. DHHC showed good adsorption potential for Ni(II) ions. The optimum initial pH value was selected as 5.0. The experimental data fitted well to the Langmuir adsorption isotherm model. Among the kinetic models tested for the adsorption of Ni(II), the pseudo-second-order model showed a good fit of the kinetic data. The thermodynamic parameters including the Gibbs free energy (Delta G), enthalpy (Delta H), and entropy (Delta S) changes indicated that the adsorption of Ni(II) ions onto DHHC was feasible, spontaneous, and exothermic in the temperature range of 25-55 degrees C. The results of this study showed the effectiveness and feasibility of DHHC for the removal of Ni(II) ions from aqueous solution.