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Reaction of 9-oxabicyclo[4.2.1]non-7-ene-1-ol with tetrazine: An unusually facile intramolecular rearrangement

Kaya, Afsin A.; Salamci, Emine; Menzek, Abdullah; Erdem, Safiye S.; Sahin, Ertan; Ecer, Kadriye (Pergamon-Elsevier Science Ltd, 2017)

Reaction of (1S(*), 7R(*))-9-oxabicyclo[4.2.1]non-7-en-1 -ol (5) with dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate (6) produced (2R(*),4R(*))-dimethyl 4-(7-oxooxepan-2-yl)-1,4-dihydropyridazine-3,6-dicarboxylate (11) in a ...