Separation and preconcentration of lead, chromium and copper by using with the combination coprecipitation-flame atomic absorption spectrometric determination

Abstract

A coprecipitation method was developed for the quantitative separation and preconcentration of Pb(II), Cr(III) and Cu(II) ions. Analytes were coprecipitated using a triazole derivative (2-{4-[2-(1H-indol-3-yl)ethyl]-3-(4-chlorobenzyl)-5-oxo-4,5-dihydro-1H-1,2,4-triazol-1-yl}-N-aryl methylidene acetohydrazid). The analytes were analyzed by flame atomic absorption spectrometry. The parameters such as sample pH, amount of reagent, sample volume, matrix effects etc. were investigated. The enrichment factor for the analyzed metal ions was obtained as 50. The relative standard deviations (RSD) were in the range of 2.8-4.1%. The accuracy of the proposed procedure was checked by the analysis of the CRM-CSandy Soil C. The method was successfully applied to real samples. (C) 2013 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.